1. Ntau yam khoom ntawm cesium carbonate nyob rau hauv cov organic synthesis los ntawm cov mos Lewis acidity ntawm cesium ion, uas ua rau nws soluble nyob rau hauv organic solvents xws li cawv, DMF thiab ether.
2. Qhov zoo solubility nyob rau hauv cov kuab tshuaj organic enables cesium carbonate raws li ib tug zoo inorganic puag koom nyob rau hauv cov tshuaj tiv thaiv catalyzed los ntawm palladium reagents xws li Heck, Suzuki thiab Sonogashira cov tshuaj tiv thaiv. Piv txwv li, Suzuki cross-coupling cov tshuaj tiv thaiv tuaj yeem ua tiav cov txiaj ntsig ntawm 86% nrog kev txhawb nqa ntawm cesium carbonate, thaum cov txiaj ntsig ntawm tib cov tshuaj tiv thaiv nrog kev koom tes ntawm sodium carbonate lossis triethylamine tsuas yog 29% thiab 50%. Ib yam li ntawd, nyob rau hauv Heck cov tshuaj tiv thaiv ntawm methacrylate thiab chlorobenzene, cesium carbonate muaj qhov zoo ntawm lwm cov hauv paus inorganic, xws li potassium carbonate, sodium acetate, triethylamine, thiab potassium phosphate.
3. Cesium carbonate kuj tseem muaj daim ntawv thov tseem ceeb hauv kev paub txog O-alkylation cov tshuaj tiv thaiv ntawm phenol tebchaw.
4. Cov kev sim xav tias phenol O-alkylation cov tshuaj tiv thaiv nyob rau hauv cov kuab tshuaj uas tsis yog aqueous tshwm sim los ntawm cesium carbonate yuav muaj kev paub txog phenoloxy anions, yog li cov tshuaj tiv thaiv alkylation kuj tuaj yeem tshwm sim rau cov kev ua haujlwm siab theem nrab halogens uas muaj feem cuam tshuam rau kev tshem tawm cov tshuaj tiv thaiv. .
5. Cesium carbonate kuj tseem muaj kev siv tseem ceeb hauv kev tsim cov khoom ntuj tsim. Piv txwv li, nyob rau hauv cov synthesis ntawm Lipogrammisin-A compound nyob rau hauv lub kauj ruam tseem ceeb ntawm lub nplhaib-kaw cov tshuaj tiv thaiv, kev siv cov cesium carbonate raws li ib tug inorganic puag yuav tau kaw-ntiv nplhaib cov khoom nrog high yields.
6. Tsis tas li ntawd, vim yog qhov zoo solubility ntawm cesium carbonate hauv cov kuab tshuaj organic, nws kuj tseem muaj kev siv tseem ceeb hauv cov khoom siv txhawb nqa organic. Piv txwv li, peb cov tshuaj tiv thaiv ntawm aniline thiab cov khoom txhawb nqa halide yog induced nyob rau hauv ib tug carbon dioxide cua los ua ke carboxylate los yog carbamate tebchaw nrog high yield.
7. Nyob rau hauv microwave hluav taws xob, cesium carbonate kuj tuaj yeem siv los ua lub hauv paus kom paub txog cov tshuaj tiv thaiv esterification ntawm benzoic acid thiab cov khoom txhawb nqa halogens.
