Excellent quality Manufacturer Supplier Niobium(V) Chloride Cl5nb Powder - Cesium carbonate 534-17-8 – Starsky

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Excellent quality Manufacturer Supplier Niobium(V) Chloride Cl5nb Powder - Cesium carbonate 534-17-8 – Starsky Detail:

Description

Product Name: Cesium carbonate

CAS: 534-17-8

MF: CCs2O3

MW: 325.82

EINECS: 208-591-9

Density: 4.072

Form: Powder/Granules

Color: White

Specific Gravity: 4.072

Sensitive: Hygroscopic

Merck: 14,2010

BRN: 4546405

Specification

Product Name

Cesium carbonate

Appearance

White crystalline powder

Purity

99.9%

Melting point

610°C

Boiling point

333.6ºC at 760 mmHg

Flash point

169.8ºC

Water solubility

261 g/100 mL (20 ºC)

Application

1. Many properties of cesium carbonate in organic synthesis come from the soft Lewis acidity of cesium ion, which makes it soluble in organic solvents such as alcohol, DMF and ether.

2. The good solubility in organic solvents enables cesium carbonate as an effective inorganic base to participate in chemical reactions catalyzed by palladium reagents such as Heck, Suzuki and Sonogashira reactions. For example, the Suzuki cross-coupling reaction can achieve a yield of 86% with the support of cesium carbonate, while the yield of the same reaction with the participation of sodium carbonate or triethylamine is only 29% and 50%. Similarly, in the Heck reaction of methacrylate and chlorobenzene, cesium carbonate has obvious advantages over other inorganic bases, such as potassium carbonate, sodium acetate, triethylamine, and potassium phosphate.

3. Cesium carbonate also has a very important application in realizing the O-alkylation reaction of phenol compounds.

4. Experiments speculate that the phenol O-alkylation reaction in non-aqueous solvents induced by cesium carbonate is likely to have experienced phenoloxy anions, so the alkylation reaction can also occur for high-activity secondary halogens that are prone to elimination reactions. .

5. Cesium carbonate also has important uses in the synthesis of natural products. For example, in the synthesis of Lipogrammistin-A compound in the key step of the ring-closing reaction, the use of cesium carbonate as an inorganic base can obtain closed-ring products with high yields.

6. In addition, due to the good solubility of cesium carbonate in organic solvents, it also has important uses in solid-supported organic reactions. For example, the three-component reaction of aniline and solid-supported halide is induced in a carbon dioxide atmosphere to synthesize carboxylate or carbamate compounds with high yield.

7. Under microwave radiation, cesium carbonate can also be used as a base to realize the esterification reaction of benzoic acid and solid-supported halogens.

Storage

low-temperature, ventilated and dry warehouse

Stability

stable. Incompatible materials: strong oxidants, strong acids.


Product detail pictures:

Excellent quality Manufacturer Supplier Niobium(V) Chloride Cl5nb Powder - Cesium carbonate 534-17-8 – Starsky detail pictures

Excellent quality Manufacturer Supplier Niobium(V) Chloride Cl5nb Powder - Cesium carbonate 534-17-8 – Starsky detail pictures

Excellent quality Manufacturer Supplier Niobium(V) Chloride Cl5nb Powder - Cesium carbonate 534-17-8 – Starsky detail pictures

Excellent quality Manufacturer Supplier Niobium(V) Chloride Cl5nb Powder - Cesium carbonate 534-17-8 – Starsky detail pictures


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Fast and great quotations, informed advisers to help you choose the correct solution that suits all your requirements, a short creation time, responsible top quality manage and distinct providers for paying and shipping affairs for Excellent quality Manufacturer Supplier Niobium(V) Chloride Cl5nb Powder - Cesium carbonate 534-17-8 – Starsky, The product will supply to all over the world, such as: Sierra Leone, Jordan, Malaysia, Many years of work experience, we have realized the importance of providing good quality products and the best before-sales and after-sales services. Most problems between suppliers and clients are due to poor communication. Culturally, suppliers can be reluctant to question things they do not understand. We break down those barriers to ensure you get what you want to the level you expect, when you want it. faster delivery time and the product you want is our Criterion .
  • Products and services are very good, our leader is very satisfied with this procurement, it is better than we expected,
    5 Stars By Polly from Luxembourg - 2018.10.09 19:07
    The customer service staff is very patient and has a positive and progressive attitude to our interest, so that we can have a comprehensive understanding of the product and finally we reached an agreement, thanks!
    5 Stars By Dawn from Zurich - 2017.04.18 16:45

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